PH of Solutions and Buffers

Report / Improvement Versions | 1.0.0
Input Parameters
Field Guide
Solution Type
Choose the type of solution to calculate pH for
Concentration (mol/L)
Total analytical concentration of the acid, base, or major buffer component
pKa (for weak acid/base/buffer)
pKa of the weak acid (acidic buffer) or conjugate acid (basic buffer). Not needed for strong types.
Buffer Ratio [A⁻]/[HA] or [B]/[BH⁺]
Only for buffers: ratio of conjugate base to acid (acidic) or free base to conjugate acid (basic)

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Formulas & Detailed Explanation

This tool calculates the pH and pOH of aqueous solutions for strong and weak acids, strong and weak bases, as well as acidic and basic buffer systems at 25°C.

Users select the solution type, enter the concentration, pKa (when required), and buffer ratio (for buffers). The tool instantly provides the exact pH, pOH, [H⁺], and [OH⁻] values along with the underlying calculation method.

The calculations use the following equations:

Strong acids:   \[ \text{pH} = -\log C \]

Strong bases:   \[ \text{pOH} = -\log C \quad \Rightarrow \quad \text{pH} = 14 - \text{pOH} \]

Weak acids (with quadratic solution when approximation is insufficient):   \[ [\ce{H+}] \approx \sqrt{K_a \cdot C} \]   Exact: solution of \( K_a = \frac{[\ce{H+}][\ce{A-}]}{[\ce{HA}]} \)

Weak bases (via conjugate acid pKa):   \[ K_b = \frac{K_w}{K_a} \quad , \quad [\ce{OH-}] \approx \sqrt{K_b \cdot C} \]

Acidic buffers (HA + A⁻):   \[ \text{pH} = \text{p}K_a + \log\left(\frac{[\ce{A-}]}{[\ce{HA}]}\right) \]

Basic buffers (B + BH⁺):   \[ \text{pH} = \text{p}K_a + \log\left(\frac{[\ce{B}]}{[\ce{BH+}]}\right) \]

where \( K_w = 1.0 \times 10^{-14} \) at 25°C.

The tool also displays a pH gauge and titration curves to visualize behavior during acid-base titrations.

Ideal for predicting solution acidity, designing buffers, planning titrations, and educational use in general, analytical, and pharmaceutical chemistry.

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